Electrophoretic NMR assembly
Extending the capability of conventional NMR instruments
Well-established scientific background and proven technology
Operates as add-on with any conventional NMR spectrometer and gradient-capable probe; requires no additional hardware or software
Advanced sample cell and RF filter system
Straightforward embedding of voltage pulses in conventional NMR pulse programs, ready-made pulse programs
Probe and user protection system
Physical chemistry – ion pairing and association in simple and complex (polyelectrolytes) ionic mixtures.
Batteries and fuel cells - chemically selective measurement of ionic migration.
Biochemistry – biomolecular charge and association.
Analytical chemistry – electrophoretic analysis of complex ionic mixtures
Pharmaceutical chemistry – release and association of charged drugs
Metallorganic chemistry – the structure of supramolecular complexes from the observed charge
P. C. Griffiths, in Annual Reports on NMR Spectroscopy, ed. A. W. Graham, Academic Press, 2009, vol. 65, p. 139.
F. Hallberg, I. Furó, P. V. Yushmanov and P. Stilbs, Sensitive and robust electrophoretic NMR. Instrumentation and experiments, J. Magn. Reson. 192 69-77 (2008).
F. Hallberg, C. F. Weise, P. V. Yushmanov, E. Thyboll Pettersson, P. Stilbs and I. Furó, Molecular complexation and binding studied by electrophoretic NMR spectroscopy, J. Am. Chem. Soc.130 7550-7551 (2008).
F. Hallberg, I. Furó and P. Stilbs, Ion pairing in ethanol/water solution probed by electrophoretic and diffusion NMR, J. Am. Chem. Soc.131 13900-13901 (2009).
F. Hallberg, T. Vernersson, E. Thyboll Pettersson, S. V. Dvinskikh, G. Lindbergh and I.Furó, Electrokinetic transport of water and methanol in Nafion membranes as observed by NMR spectroscopy, Electrochim. Acta55 3542–3549 (2010).
M. Giesecke, Z. Szabó, and I. Furó, The protonation state and binding mode in a metal coordination complex from the charge measured in solution by electrophoretic NMR, Anal. Methods5 1648 - 1651 (2013).
M. Bielejewski, M. Giesecke and I. Furó, On electrophoretic NMR. Exploring high conductivity samples, J. Magn. Reson.243 17-24 (2014).
U. Scheler, in Encyclopedia of Magnetic Resonance, ed. R. K. Harris and R. Wasylishen, Wiley, 2012, DOI: 10.1002/9780470034590.emrstm0154.